PurpleCAT

Periodic Table

MetalNonmetalTransition MetalHalogenNoble GasMetalloid
Electronegativity & Ionization Energy increase
Atomic Radius & Metallic Character increase
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
57–71
89–103
Electronegativity & IE decrease
Atomic Radius & Metallic Character decrease

Periodic Trends

Three of the four trends point the same way (toward the top right); atomic radius and metallic character are the opposite.

Across a period (left to right)

EN and IE increase; atomic radius and metallic character decrease.

Down a group (top to bottom)

Atomic radius and metallic character increase; EN and IE decrease.

Atomic Radius

Decreases left to right Increases top to bottom
Why

Across a row, protons increase while electrons fill the same shell, so the stronger nuclear pull draws the electron cloud inward. Down a group, each new period adds a shell, so electrons sit farther from the nucleus.

On the MCAT

You will rarely calculate a radius. Instead you rank or compare atoms and ions. Remember cations are smaller than their neutral atom (lost a shell / less repulsion) and anions are larger (added electrons / more repulsion).

Metallic Character

Decreases left to right Increases top to bottom
Why

Metallic character tracks how easily an atom gives up electrons. It follows atomic radius: larger, looser atoms (bottom left) lose electrons easily and are the most metallic, while small, tightly held nonmetals (top right) are the least.

On the MCAT

Used to predict reactivity of metals and whether an element forms cations. Francium/cesium region is most metallic, fluorine region is least. Metalloids sit along the staircase.

Electronegativity (EN)

Increases left to right Decreases top to bottom
Why

EN is an atom's pull on shared bonding electrons. A smaller atom with high nuclear charge (top right, excluding noble gases) holds bonded electrons more tightly, so EN rises toward fluorine, the most electronegative element.

On the MCAT

Drives bond polarity and dipoles. Compare EN differences to decide if a bond is nonpolar, polar covalent, or ionic, and to find the partial-negative end of a bond or the most acidic proton.

Ionization Energy (IE)

Increases left to right Decreases top to bottom
Why

IE is the energy to remove an electron. Smaller atoms with a strong nuclear pull (top right) hold electrons tightly, so more energy is needed. Larger atoms down a group release their outer electron easily.

On the MCAT

Expect large jumps in successive IE once you break into a full (noble-gas) shell, which reveals valence count. Noble gases have the highest IE; alkali metals the lowest.

MCAT® is a registered trademark of the Association of American Medical Colleges (AAMC). PurpleCAT is not affiliated with, endorsed by, or sponsored by the AAMC.